Every Year as part of the Virginia Household Water Quality
Program Prince William County Extension holds a drinking water clinics for well
owners. This year the clinic was oversubscribed and there will be a second
sampling date on June 7th . The first group of samples were taken March 29th 2017 and analyzed for: iron,
manganese, nitrate, lead, arsenic, fluoride, sulfate, pH, total dissolved
solids, hardness, sodium, copper, total coliform bacteria and E. Coli bacteria
at a cost of $55 to the well owner.
What we test for are mostly the naturally occurring
contaminants and common sources of contamination: a poorly sealed well or a
nearby leaking septic system, or indications of plumbing system corrosion.
Though this is not an exhaustive list of potential contaminants, these are the
most common contaminants that effect drinking water wells. The chart below
shows what we found in the 101 private wells tested in the first round in Prince
William County in 2017.
In order to determine if treatment is necessary, water test results should be
compared to a standard. The standard we use is the
U.S.EPA Safe
Drinking Water Act (SDW)
limits. Though private wells do not fall under the regulatory authority of the
U.S. Environmental Protection Agency (EPA) or the Safe Drinking Water Act, the
SDW act has primary and secondary drinking water standards that we use for
comparison. Primary standards are ones that can impact health and from the
tested substances include: coliform bacteria, E. coli bacteria, nitrate, lead,
and arsenic. Secondary standards impact taste or the perceived quality of
the water.
As in last year, the 2017 Prince William County water clinic found that almost 28%
of the wells tested present for coliform bacteria-this was a lower percentage
than the overall program finds. Coliform bacteria are not a health threat
itself, it is used to indicate other bacteria that may be present and identify
that a well is not properly sealed from surface bacteria. The federal standard for
coliform bacteria is zero, but the federal standard allows that up to 5% of
samples can test positive for coliform during a month.
Four of the homes tested positive for E coli. Fecal coliform and E. coli are
bacteria whose presence indicates that the water is contaminated with human or
animal wastes. Disease-causing microbes (pathogens) in these wastes can cause
diarrhea, cramps, nausea, headaches, or other symptoms. These pathogens may
pose a special health risk for infants, young children, and those with
compromised immune systems. However, people can drink water contaminated with
fecal bacteria and not notice. If your water is contaminated with coliform but
not fecal coliform or E. coli, then you have a nuisance bacteria problem and
the source may be infiltration from the surface from rain or snow melt. Typical
causes are improperly sealed well cap, failed grouting or surface drainage to
the well. Shock chlorinate the well, repack the soil around the well pipe to
flow away from the well and replace the well cap. Then after the next big
rainstorm retest the well for coliform. If it is still present then a long-term
treatment should be implemented: using UV light, ozonation, or chlorine for
continuous disinfection. These systems can cost up to $2,000 installed.
If you have fecal coliform in the well or E. coli, your well is being impacted
by human or animal waste and you are drinking dilute sewage. If there is not a
nearby animal waste composting facility, then you are probably drinking water
from a failed septic system- yours or your nearest neighbors. To solve this
problem you need to fix or replace the septic system that is causing the
contamination, replace the well or install a disinfection and filtration
system. Disinfection does not kill Giardia or Cryptosporidium, two microscopic
parasites that can be found in groundwater that has been impacted by surface
water or sewage. Both parasites produce cysts that cause illness and sometimes
death.
Membrane filtration is the usual treatment for these parasites- a one micron
membrane is required after disinfection and can be accomplished at home with a
reverse osmosis system. The failing septic systems can often be identified by
using tracer dyes. While continuous disinfection will work to protect you from fecal
bacteria and E. coli, be aware that if your well is being impacted by a septic
system, then the well water might also have present traces of all the chemicals
and substances that get poured down the drain. Long term treatment for
disinfection, and micro-filtration should be implemented: using UV light,
ozonation, or chlorine for continuous disinfection, carbon filtration, and
anything that is used for drinking should be further treated with a reverse
osmosis systems or micro membrane system that work by using pressure to force
water through a semi-permeable membrane. Large quantities of wastewater are
produced by reverse osmosis systems and need to bypass the septic system or
they will overwhelm that system creating more groundwater problems. Reverse osmosis
systems produce water very slowly, a pressurized storage tank and special
faucet needs to be installed so that water is available to meet the demand for
drinking and cooking.
Nitrate can contaminate well water from fertilizer use; leaking from septic
tanks, sewage and erosion of natural deposits. None of the wells in our group
of 101 samples had nitrate levels above the MCL. The MCL for nitrate is 10 mg/L.
Infants below the age of six months who drink water containing nitrate in
excess of the MCL could become seriously ill from blue-baby syndrome and, if
untreated, may die. Symptoms include shortness of breath and a blue ting to the
skin common in blue-baby syndrome. The NO3 dissolves and moves easily through
soil which varies seasonally and over time as plants use up the nitrate over
the summer. Testing in the spring will usually produce the highest levels.
Nitrate may indicate contamination from septic tanks, but do not boil the
water- boiling water reduces the water and actually INCREASES the concentration
of nitrates. Reverse osmosis, or ion exchange is necessary to control the
nitrate.
In years past the water clinic has found almost 20% of wells tested positive
for lead. This year we had 6.9% of homes have first flush lead levels above the
SDWA maximum contaminant level of 0.015 Mg/L. After the first flush only two
homes had lead levels above the 0.15 mg/L level; however, many scientists do
not believe that any level of lead is safe to drink over an extended period of
time. In the homes that had elevated lead in the first draw, it tends to be negatively
correlated with pH values. Houses built before 1988 when the ban on lead went
into effect and had low pH water had higher lead concentrations. Lead leaches
into water primarily as a result of corrosion of plumbing and well components,
but can also result from flaking of scale from brass fittings and well
components unrelated to corrosion and corrosion control techniques such as
adjusting pH or alkalinity that are commonly used to neutralize aggressive
water will not work in those cases. For most instances, though, a neutralizing
filter and lead removing activated carbon filters can be used to remove lead.
Recently, some home water treatment companies are offering in home treatment
systems that neutralize the water and add orthophosphate other phosphate
solution to coat the piping to prevent further corrosion. It should work, but I
have never seen such a home system and am not aware of any testing. It is
important to note that elevated lead concentrations were still observed in
homes built after 1988 and in one home with normal pH and built after 2000.
Iron and manganese are naturally occurring elements commonly found in
groundwater in this part of the country. 9.9% of the wells tested exceed the
iron standard and 4% exceeded the manganese standard. At naturally occurring
levels iron and manganese do not present a health hazard. However, their
presence in well water can cause unpleasant taste, staining and accumulation of
mineral solids that can clog water treatment equipment and plumbing and
discolored water. The standard Secondary Maximum Contaminant Level (SMCL) for
iron is 0.3 milligrams per liter (mg/L or ppm) and 0.05 mg/L for manganese.
This level of iron and manganese are easily detected by taste, smell or
appearance. In addition, some types of bacteria react with soluble forms of
iron and manganese and form persistent bacterial contamination in a well, water
system and any treatment systems. These organisms change the iron and manganese
from a soluble form into a less soluble form, thus causing precipitation and
accumulation of black or reddish brown gelatinous material (slime). Masses of
mucous, iron, and/or manganese can clog plumbing and water treatment equipment.
All
systems of removing iron and manganese essentially involve oxidation of the
soluble form or killing and removal of the iron bacteria. When the
total combined iron and manganese concentration is less than 15 mg/l, an
oxidizing filter is the recommended solution. An oxidizing filter supplies
oxygen to convert ferrous iron into a solid form which can be filtered out of
the water. Higher concentrations of iron and manganese can be treated with an
aeration and filtration system. This system is not effective on water with
iron/ manganese bacteria, but is very effective on soluble iron and manganese
so you need to do further testing to determine what type of iron/manganese you
have before you install a treatment system. Water softeners can remove low
levels of iron, but are not recommended for just this purpose. Chemical
oxidation can be used to remove high levels of dissolved or oxidized iron and
manganese as well as treat the presence of iron/manganese (or even sulfur)
bacteria. The system consists of a small pump that puts an oxidizing agent into
the water before the pressure tank. The water will need about 20 minutes for
oxidation to take place so treating before a holding tank or pressure tank is a
must. After the solid particles have formed the water is filtered. The best
oxidizing agents are chlorine or hydrogen peroxide. If chlorine is used, an
activated carbon filter is often used to finish the water and remove the
chlorine taste. The holding tank or pressure tank will have to be cleaned
regularly to remove any settled particles.
The pH of water is a measure of the acidity or alkalinity. The pH is a
logarithmic scale from 0 – 14 with 1 being very acidic and 14 very alkaline.
Drinking water should be between 6.5 and 7.5. For reference and to put this
into perspective, coffee has a pH of around 5 and salt water has a pH of around
9. Corrosive water, sometimes also called aggressive water is typically water
with a low pH. (Alkaline water can also be corrosive.) Low pH water can corrode
metal plumbing fixtures causing lead and copper to leach into the water and
causing pitting and leaks in the plumbing system. The presence of lead or
copper in water is most commonly leaching from the plumbing system rather than
the groundwater. Acidic water is easily treated using an acid neutralizing
filter. Typically these neutralizing filters use a granular marble, calcium
carbonate or lime. If the water is very acidic a mixing tank using soda ash,
sodium carbonate or sodium hydroxide can be used. The acid neutralizing filters
will increase the hardness of the water because of the addition of calcium
carbonate. The sodium based systems will increase the salt content in the
water. 9.9% of the wells tested were found to have acidic water this year. High
pH levels are not natural to groundwater and typically result from salt water
intrusion or over treatment with water softening system and/acid neutralizing
systems. There were two homes where this turned out to be the case.
Water that contains high levels of dissolved minerals is commonly referred to
as hard. Groundwater very slowly wears away at the rocks and minerals picking
up small amounts of calcium and magnesium ions. Water containing approximately
125 mg/L can begin to have a noticeable impact and is considered hard.
Concentrations above 180 mg/L are considered very hard. As the mineral level
climbs, bath soap combines with the minerals and forms a pasty scum that
accumulates on bathtubs and sinks. You either must use more soap and detergent
in washing or use specially formulated hard water soap solutions. Hard water
can be just a minor annoyance with spotting and the buildup of lime scale, but
once water reaches the very hard level 180 mg/L or 10.5 grains per gallon, it
can become problematic. This year we had a well test at 505.7 mg/L, but overall
on 15.8% of homes tested had hard water. Given the number of homes with
elevated sodium and our local geology, it is probably a reflection of the
number of homes with water softeners.
Water softening systems are used to address the problem are basically an ion
exchange system. The water softening system consists of a mineral tank and a
brine tank. The water supply pipe is connected to the mineral tank so that
water coming into the house must pass through the tank before it can be used.
The mineral tank holds small beads of resin that have a negative electrical
charge. The calcium and magnesium ions are positively charged and are attracted
to the negatively charged beads. This attraction makes the minerals stick to
the beads as the hard water passes through the mineral tank. Sodium is often used
to charge the resin beads. Water softeners can be used to remove small amounts
of other metals like iron and some forms of arsenic. As the water is softened,
the sodium ions are replaced and small quantities of sodium are released into
the softened water, thus the salty taste of softened water. When the water
softening system is recharged the excess sodium solution carrying the calcium
and magnesium is flushed to the septic system which may shorten the life of the
drain field.
At the present time the EPA guidance level for
sodium
in drinking water is 20 mg/L. This level was developed for those
restricted to a total sodium intake of 500 mg/day and does not necessarily
represent a necessary level for the rest of the population. Based on taste of
the water levels of sodium should be below 30 to 60 mg/L based on individual
taste. Water softeners ten to cost around $4,500 installed. They are often sold
to solve every water quality problem because they have some ability to remove
other contaminants. The resin bed used will determine specific contaminant
removal. Softened water can have a low pH and high levels of chloride,
corrosion control problems and softening systems can encourage the growth of
reducing bacteria. Water softening systems add sodium. Reverse osmosis systems
and distillation systems remove sodium and are safe for household use, but
addressing hard water by using vinegar to descale pots and dishwashers,
regularly draining hot water heaters, and using detergents formulated for hard
water might be a better solution for you if your water like mine is only
modestly hard.
For the second time this year we found a well that had arsenic exceeding the EPA
MCL for drinking water of 10 ppm. While arsenic is a naturally occurring
element found in soil and groundwater it is not typically found at
significantly elevated levels in Prince William County. Arsenic can also be an
indication of industrial or pesticide contamination and further testing should
be done. Arsenic can be very tricky to remove depending on its form and the
other contaminants present. Possible solutions for elevated levels of naturally
occurring arsenic are reverse osmosis system, iron oxide filter system, or
maybe a water softening system.