Where carbonate rocks are exposed at land surface or are overlain by only a thin layer of confining material they are easily dissolved by rain. As rain falls it absorbs some carbon dioxide from the atmosphere and from organic matter in soil. As the water percolates through the soil the weak carbonic acid water dissolves limestone and dolomite by enlarging pores between grains of limestone or fractures in the rock.
Over time these openings become larger as more of the acidic water moves through the aquifer; eventually the openings may be tens of feet in diameter. The end result of dissolution of carbonate rocks is a type of topography called karst- characterized by caves and sinkholes.
Water-supply wells drilled into the carbonate aquifers in karst terrain are generally more productive than wells that tap other rock types. The carbonate aquifers, due to the presence of dissolution channels, are very vulnerable to contamination from the surface. The carbonate aquifers are particularly vulnerable where sinkholes allow for the relatively rapid movement of contaminants into and through the aquifer. In some areas, the carbonate aquifers are locally isolated from the surface by thick layers of clay or shale that can impede the downward movement of water and contaminants.
The carbonate aquifers of the Appalachian Valley and Ridge Province, formed during Appalachian mountain building, have highly variable karst aquifer characteristics. The Valley and Ridge, Piedmont, and Blue Ridge Aquifers demonstrate karst features such as caves, sinkholes, sinking streams, and conduits. They are still used as a major drinking water supply for individuals and public supply, but without careful management these wells can become problematic.
The combined Valley and Ridge and Piedmont and Blue Ridge aquifers of all type rank second in the Nation as a source of groundwater for private domestic supply, providing about 470 million gallons per day (Arnold and others, 2016). The Valley and Ridge and Piedmont and Blue Ridge aquifers are also an important source of public supply, providing about 195 million gallons per day. Land use overlying the Valley and Ridge and Piedmont and Blue Ridge aquifers is mostly undeveloped (49 %), agricultural (35 %), and urban land (17 %).
Valley and Ridge and Piedmont and Blue Ridge aquifers in Virginia and were evaluated by the USGS National Water-Quality Assessment Project, which began in2012 and continued through 2021. Below are excerpts from that evaluation. The above information was taken from the USGS Groundwater Atlas of the United States.
Samples were analyzed for 34 trace elements and major and minor ions. Contaminants from this group were detected at high concentrations in about 10 % of the study area (at the depth zone used for public supply) and at moderate concentrations in about 5 %. Arsenic, manganese, and strontium were the only trace elements detected at high concentrations.
Samples were analyzed for eight radioactive contaminants, of which four have human-health benchmarks. Radioactive constituents were detected at high levels in about 3 % of the study area, but were not detected at moderate levels. Gross alpha activity was the only constituent detected at high concentrations.
Samples were analyzed for five nutrients, of which two have human-health benchmarks. Common sources of nutrients include fertilizer applied to crops and landscaping, seepage from septic systems, and human and animal waste. Nutrients were detected at high concentrations in about 2 % of the study area and at moderate concentrations in about 11 %. Nitrate was the only nutrient detected at high concentrations.
Some constituents affect the aesthetic properties of water, such as taste, color, and odor, or can create nuisance problems, such as staining and scaling. Samples were analyzed for 11 constituents that have SMCLs. One or more of these were present at high concentrations or values relative to the SMCL in about 15 % of the study area and at moderate concentrations in about 18 %.
Total dissolved solids (TDS) concentration is a measure of the salinity of the groundwater, and all water naturally contains TDS as a result of the weathering and dissolution of minerals in rocks and sediments. The TDS concentrations can be high because of natural factors or as a result of human activities, such as applications to the land surface of road salt, fertilizers, or other chemicals in urban or agricultural areas. The TDS concentrations were high in about 5 % of the study area.
Iron and manganese were both present at high concentrations relative to the SMCL in about 5 % of the study area. Sulfate was present at high concentrations in about 2 % of the study area. In a few samples, the pH of groundwater was not in the SMCL range of 6.5–8.5. In those cases, the pH was less than 6.5; such waters are considered acidic and potentially corrosive.
VOCs were detected at moderate concentrations in 2 percent of the study area. The only VOC detected at moderate concentrations was chloroform.
Samples were analyzed for 227 pesticide compounds (pesticides and their breakdown products), of which 119 have human-health benchmarks. Pesticide compounds were not detected at high or moderate concentrations in the study area.
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