Wednesday, December 11, 2024

EPA bans TCE and Phases out PERC

On Monday, the U.S. Environmental Protection Agency (EPA) finalized the latest risk management rules for trichloroethylene (TCE) and perchloroethylene (PCE) . The final EPA rules bans all uses of TCE, all consumer uses and many commercial uses of PCE, require worker protections for all remaining uses under the Toxic Substances Control Act.

TCE is an extremely toxic chemical known to cause liver cancer, kidney cancer, and non-Hodgkin’s lymphoma. TCE also causes damage to the central nervous system, liver, kidneys, immune system, reproductive organs, and fetal heart defects. These risks are present even at very small concentrations. Under today’s rule, all uses of TCE will be banned over time (with the vast majority of identified risks eliminated within one year), and safer alternatives are readily available for the majority of uses.

PCE is known to cause liver, kidney, brain and testicular cancer, as well as damage to the kidney, liver and immune system, neurotoxicity, and reproductive toxicity. Today’s final rule will better protect people from these risks by banning manufacture, processing and distribution in commerce of PCE for all consumer uses and many commercial uses, while allowing some workplace uses to continue only where robust workplace controls can be implemented.

PCE and TCE are both nonflammable chlorinated solvents that are volatile organic compounds. PCE can biodegrade into TCE, and PCE may contain trace amounts of TCE as an impurity or a contaminant. The chemicals can often serve as alternatives for each other. For several uses of TCE that will be totally prohibited, there is an analogous use of PCE that can continue safely in perpetuity under workplace controls. Some examples of uses that will be prohibited under the TCE rule, but will continue under the PCE rule include: industrial and commercial use as an energized electrical cleaner, in laboratory use for asphalt testing and recovery, use to make refrigerants and other chemicals, and for vapor degreasing. 

EPA had previously banned the use of TCE in dry cleaning. Though TCE was introduced as a dry cleaning solvent in the United States in 1930, it was never widely used for that purpose.  TCE was found to cause the bleeding of some acetate dyes at temperatures above 75 degrees Fahrenheit. Instead it was widely used as a dry-side pre-cleaning or spotting agent and in water repellent agents. Nothing removes lipstick from silk like a dab of TCE and it was the principle ingredient in various spot removers.

There have been several well documented cases of health impacts from TCE contamination. It is truly tragic that a cancer cluster among children in Woburn,  MA over 40 years ago became  a crusade by one of the mothers to keep any more children like her son from dying from cancer caused by toxic chemicals. Camp Lejeune lawsuit for injuries, birth defects and deaths from water contamination in the water supply at the Marine Corp base is the most famous thanks in a large part to the unrelenting advertising by personal injury lawyers. In case you don't know what that is about, the story began in 1980.

At that time when in compliance with brand new regulations from the young U.S. Environmental Protection Agency, PA, the base began testing the water for trihalomehtanes. That same year, a laboratory from the U.S. Army Environmental Hygiene Agency began finding contamination from halogenated hydrocarbons in the water. In March 1981 one of the lab's reports, which was delivered to U.S. Marine officials, informed them that the drinking water was highly contaminated with other chlorinated hydrocarbons (solvents).

Possible sources of the contamination were identified as solvents from a nearby, off-base dry cleaning company, from on-base units using solvent to degrease motors and other military equipment, and leaks from underground fuel storage tanks.

In 1982 the USMC hired a private company, Grainger Laboratories, to examine the problem. They provided the base commander with a report showing that the drinking water wells supplying water for the base were contaminated with PCE and TCE, the solvents used in drycleaning and equipment maintenance. The contractor delivered repeated warnings to base officials and was fired after delivering written warnings in December 1982, March 1983, and September 1983.

In a spring 1983 report to the EPA, Lejeune officials stated that there were no environmental problems at the base- they knowingly lied. In June 1983, North Carolina's water supply agency asked Lejeune officials for the lab’s reports on the water testing. Marine officials declined to provide the reports to the state agency.

In July 1984, a different company contracted by the U.S. EPA under the Superfund review of Lejeune and other military sites found benzene in the base's water, along with PCE and TCE. Marine officials shut down one of the contaminated wells at Camp Legeune in November 1984 and the others in early 1985. The Marines notified North Carolina of the contamination in December 1984. At this time the Marines did not disclose that benzene had been discovered in the water and stated to the media that the EPA did not find unacceptable levels of PCE and TCE. Ultimately, it all came out as it always does. 

Another instance  is what happened in Sterling, Virginia. The short story is that for twenty or thirty years homeowners in that community in in Loudoun County were drinking water contaminated with TCE and its degradation products. The homes had been built on and old landfill and back in 1988 the Loudoun County Department of Health and the EPA had found traces of TCE, its degradation products and pesticides in three residential wells, but because the contamination was below the regulated maximum contaminant level (MCL) no further investigation was performed. Apparently, the oddity of finding a solvent in groundwater in a residential community did not immediately prompt further investigation. The water was within safe limits and thus was fine.

However, the water in the neighborhood was not fine. In 2005, 68 more wells (in the community) were tested by the Health Department. “Forty-five wells tested positive for TCE; 17 of these wells contained concentration of TCE above the maximum contaminant level (MCL) of 5 micrograms per liter (mcg/L) while 28 wells contained TCE, but below the MCL.”  The site was declared a CERCLA (Superfund) site in 2008. Between 1988 and 2005 no testing was done on the individual homeowner wells. The water was consumed by the young and old and the homes were bought and sold. If your home had been declared within a Superfund site, it is very likely that the value of the home would be impacted.

Everything that is known about the groundwater in Prince William County is because a study of the groundwater was performed by the U.S. Geological Survey (USGS) in 1991 to study the extent of TCE contamination from the Superfund site in Manassas. They did not test every inch of the county nor look for other contaminants, but felt that they were able to find the extent of the TCE contamination plume.

To be prudent and smart you need to test a well for likely sources of contamination. When I was working as an Environmental Engineer, the biggest challenge was to adequately research the history of a property and then test the soil and groundwater for contamination in the areas most likely to be contaminated. Testing is expensive, so it is virtually impossible to fully test soil and groundwater for everything and it is very easy to miss the contamination if the study is not planned properly and you do not understand the geology. Knowing the history of an area is the only shot you have of identifying likely contaminants.

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